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ASSESSMENT OF THERMODYNAMIC DATA AND STABILITY OF INTERMETALLIC COMPOUNDS

LI Wenchao , LI Xingkang , WANG Jian , ZHOU Guozhi (University of Science and Technology Beijing , Beijing , China)SUN Guiru (General Research Institute for Non-Ferrous Metals , Beijing 100088 , China Manuscript received 5 January , 1995)

金属学报(英文版)

Based on principles of thermodynamics, it is derivd that in binary system the quasi-parabola regulation must be obeyedby the standard Gibbs free energy of formation of a compound.Extending to ternary system a quasi-paraboloid regulation also must be done. The stability of some intermetallic compounds in binary systems is decided

关键词: : standard Gibbs free energy , null , null

CRYSTALLOGRAPHIC PROPERTIES OF AN INHERENT LOW-ENERGY INTERFACE (11)Cu//(0001)_(AIN) IN Cu-AlN BICRYSTAL

J. Du , G.Y.Yang and S. Hagegege(General Research Institute for Non-ferrous Metals , Beijing 100088 , China)(CECM-CNRS , 15 rue G. Urbain , 94407 Vitry/Seine , France Manuscript received 25 September 1995)

金属学报(英文版)

A model Cu-AlN composite has been prepared by ion implantation technique and annealing. The atomic configuration and lattice relationship of a low-energy inherent interface(11)Cn//(0001)AlN were studied by using transmission electron microscopy and geometrical modelling. By analysing the dichromatic pattern of the composite,a primary structural unit of the interface atomic configuration was determined for purpose of HREM image simulations and of studying the structurul relaxation state in the near-interface region.

关键词: : Cu-AlN , null , null , null

Influence of Deformation and Heat Treatment on Seawater Corrosion of 70Cu-30Ni Alloy

Xiaolong ZHU(General Research Institute for Nonferrous Metals , Beijing 100088 , China)Tingquan LEI (Harbin Institute of Technology , Harbin , 150001 , China)

材料科学技术(英)

After deformed and annealed, 70Cu-30Ni alloy with irrecrystallization or incomplete recrystallization mainly consisting of deformed grains displayed unstable E.(corrosion potential) and low Rp (polarization resistance) in 3.5%NaCl, and corrosion product film contained a lot of seawater species in the outer layer and denickelified in the inner layer immersed in seawater for 3 and 6 months, and intergranular corrosion occurred in the matrix. With the increase of deformation and annealing temperature, the anodic oxide film formed by polarization in artificial seawater was increasingly stable. The recrystallized alloy was stable in Ec and high in Rp and its corrosion product film formed in seawater was uniform and rich in Ni.

关键词:

CORRELATION BETWEEN STRESS COMPONENTS AND STRESS CORROSION CRACKS IN BRASS Lecturer,Department of Materials Physics,University of Science and Technology Beijing,Beijing 100083,China

QIAO Lijie LIU Rui XIAO Jimei University of Science and Technology Beijing , Beijing , China

金属学报(英文版)

The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.

关键词: stress corrosion cracking , null , null , null

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